4.7 Article

A highly selective fluorescent sensor for mercury ions in aqueous solution: Detection based on target-induced aggregation

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 148, Issue 1, Pages 49-53

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2010.03.060

Keywords

Aggregation; Dansyl; Fluorescence enhancement; Mercury ion; Sensor

Funding

  1. Natural Science Foundation of China [20934002, 20973073]
  2. National Basic Research Program [2007CB808006]
  3. Programs for New Century Excellent Talents in University (NCET)
  4. 111 Project [B06009]

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A highly selective fluorescent probe, dansyl-L-glutamic methyl diester (1), was easily prepared for Hg2+ detection, which is aggregated by target with a blue-shift and turn-on fluorescence response. The compound also can remove the Hg2+ in aqueous solution by filtering. The involved mechanism was clarified by FTIR in the solid of crystal complex 1/Hg2+ and H-1 NMR spectra in aqueous solution. (C) 2010 Elsevier B.V. All rights reserved.

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