Application of carbon ionic liquid electrode for the electrooxidative determination of catechol

A carbon ionic liquid electrode (CILE) was constructed using graphite powder mixed with N-butylpyridinium hexafluorophosphate (BPPF6) in place of paraffin as the binder, which showed strong electrocatalytic activity to the direct oxidation of catechol. In pH 3.0 phosphate buffer solution (PBS) a pair of redox peaks appeared on the CILE with the anodic and the cathodic peak potential located at 387 and 330 mV (vs. SCE), respectively. The electrochemical behaviors of catechol on the CILE were carefully investigated, and the electrochemical parameters were calculated with the results of the electrode reaction standard rate constant k(s) as 1.27 s(-1), the charge-transfer coefficient at as 0.58 and the electron transferred number n as 2. Under the selected conditions, the anodic peak current increased linearly with the catechol concentration over the range from 1.0 x 10(-6) to 8.0 x 10(-4) mol L-1 by cyclic voltammetry at the scan rate of 100 mV s(-1). The detection limit was calculated as 6.0 x 10(-7) mol L-1 (3 sigma). The CILE showed good ability to separate the electrochemical responses of catechol and ascorbic acid (AA) with the anodic peak potential separation as 252 mV (vs. SCE). The proposed method was further applied to the synthetic samples determination with satisfactory results. (C) 2008 Elsevier B.V. All rights reserved.