4.6 Article

A Micro Oxygen Sensor Based on a Nano Sol-Gel TiO2 Thin Film

Journal

SENSORS
Volume 14, Issue 9, Pages 16423-16433

Publisher

MDPI
DOI: 10.3390/s140916423

Keywords

O-2 sensors; sol-gel; nanostructured; MEMS (Micro-Electro-Mechanical System); thin films; TiO2

Funding

  1. Natural Science Foundation of China [51175416]
  2. Major National Science and Technology Projects of China [2013ZX03005007]
  3. Basic Scientific Research Expenses of Central University [xjj2014105]

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An oxygen gas microsensor based on nanostructured sol-gel TiO2 thin films with a buried Pd layer was developed on a silicon substrate. The nanostructured titania thin films for O-2 sensors were prepared by the sol-gel process and became anatase after heat treatment. A sandwich TiO2 square board with an area of 350 mu m x 350 mu m was defined by both wet etching and dry etching processes and the wet one was applied in the final process due to its advantages of easy control for the final structure. A pair of 150 nm Pt micro interdigitated electrodes with 50 nm Ti buffer layer was fabricated on the board by a lift-off process. The sensor chip was tested in a furnace with changing the O-2 concentration from 1.0% to 20% by monitoring its electrical resistance. Results showed that after several testing cycles the sensor's output becomes stable, and its sensitivity is 0.054 with deviation 2.65 x 10(-4) and hysteresis is 8.5%. Due to its simple fabrication process, the sensor has potential for application in environmental monitoring, where lower power consumption and small size are required.

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