4.6 Article

The Assessment for Sensitivity of a NO2 Gas Sensor with ZnGa2O4/ZnO Core-Shell Nanowires-a Novel Approach

Journal

SENSORS
Volume 10, Issue 4, Pages 3057-3072

Publisher

MDPI
DOI: 10.3390/s100403057

Keywords

ZnGa2O4; ZnO; core shell; nanowire; NO2; gas sensor; sensitivity

Funding

  1. Ministry of Economic Affairs, Taiwan, R.O.C. [98-EC-17-A-02-S2-0125]

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The application of novel core-shell nanowires composed of ZnGa2O4/ZnO to improve the sensitivity of NO2 gas sensors is demonstrated in this study. The growth of ZnGa2O4/ZnO core-shell nanowires is performed by reactive evaporation on patterned ZnO:Ga/SiO2/Si templates at 600 degrees C. This is to form the homogeneous structure of the sensors investigated in this report to assess their sensitivity in terms of NO2 detection. These novel NO2 gas sensors were evaluated at working temperatures of 25 degrees C and at 250 degrees C, respectively. The result reveals the ZnGa2O4/ZnO core-shell nanowires present a good linear relationship (R-2 > 0.99) between sensitivity and NO2 concentration at both working temperatures. These core-shell nanowire sensors also possess the highest response (<90 s) and recovery (<120 s) values with greater repeatability seen for NO2 sensors at room temperature, unlike traditional sensors that only work effectively at much higher temperatures. The data in this study indicates the newly-developed ZnGa2O4/ZnO core-shell nanowire based sensors are highly promising for industrial applications.

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