Evidence for nano-Si clusters in amorphous SiO anode materials for rechargeable Li-ion batteries

Atom probe tomography and high resolution transmission electron microscopy have shown the presence of nano-sized amorphous Si clusters in non-disproportionated amorphous SiO powders are under consideration for anode materials in Li-ion batteries. After Li insertion/extraction, no change was found in the chemistry and structure of the Si clusters. However, Li atoms were found to be trapped at the amorphous SiO phase after Li insertion/extraction, which may be attributed to the large capacity fade after the first charge/discharge cycle. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.