4.7 Article

Nanoscale twinning-induced elastic strengthening in silicon carbide nanowires

Journal

SCRIPTA MATERIALIA
Volume 63, Issue 10, Pages 981-984

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2010.07.023

Keywords

Nano-twin; High pressure; Synchrotron; Silicon carbide

Funding

  1. DOE [M68008855]
  2. Los Alamos National Laboratory under DOE [DE-AC52-06NA25396]
  3. Energy Frontier Research Center funded by the DOE, Office of Science and Office of Basic Energy Sciences [DE-SC0001057]
  4. US DOE, Office of Science and Office of Basic Energy Sciences [DE-AC02-06CH11357]

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Compressibility of periodically twinned silicon carbide nanowires is studied using in situ high pressure X-ray diffraction. Twinned SiC nanowires displayed a bulk modulus of 316 GPa, similar to 20-40% higher than previously reported values for SiC of other morphologies. This finding provides direct evidence of a significant effect of twinned structures on the elastic properties of SiC on the nano scale and supports previous molecular dynamics simulations of twin boundary/stacking fault-induced strengthening. Both experiments and simulations indicate that nanoscale twinning is an effective pathway by which to tailor the mechanical properties of nanostructures. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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