Journal
SCIENCE CHINA-CHEMISTRY
Volume 62, Issue 1, Pages 62-66Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-018-9344-4
Keywords
base-catalyzed; diborylation of alkynes; cis-1; 2-bis(boryl)alkenes
Categories
Funding
- National Natural Science Foundation [21772046]
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
- Postgraduates' Innovative Fund in Scientific Research of Huaqiao University
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An efficient, transition-metal free, and practical approach to cis-bis(boryl)alkenes from various alkynes was disclosed in the presence of a catalytic amount of K2CO3 under mild conditions. Meanwhile, tetrasubstituted alkenes and phenanthrene derivatives were readily constructed from the target diborylalkenes via Suzuki-Miyaura cross coupling.
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