Journal
SCIENCE CHINA-CHEMISTRY
Volume 57, Issue 2, Pages 276-281Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-013-5024-4
Keywords
C-H bond functionalization; cyclic vinyl triflates; palladium; polyfluoroarenes
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Funding
- National Basic Research Program of China (973 Program) [2012CB821600]
- National Natural Science Foundation of China [21172242]
- Shanghai institute of Organic Chemistry
- Chinese Academy of Sciences
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An effective method for Pd-catalyzed cross-coupling between polyfluoroarenes and cyclic vinyl triflates has been developed. This protocol provides a useful and facile access to polyfluoroarylated cyclic alkenes that are difficult to prepare otherwise. The advantages of this method are its high efficiency and operational simplicity.
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