4.7 Article

Controllable self-assemblies of β-cyclodextrin-calix[4]arene couples

Journal

SCIENCE CHINA-CHEMISTRY
Volume 55, Issue 6, Pages 1092-1096

Publisher

SCIENCE PRESS
DOI: 10.1007/s11426-012-4614-x

Keywords

cyclodextrin; calixarene; self-assembly

Funding

  1. National Basic Research Program of China (973 Program) [2011CB932500]
  2. National Natural Science Foundation of China [20932004]

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Amphiphilic cyclodextrin-calixarene conjugates 1 and 2 were synthesized from click chemistry, and their self-assembly behaviors were investigated by transmission electron microscopy, and atomic force microscopy. The results obtained show that 1 and 2 can self-assemble to form distinctly different aggregations, and the morphology of aggregations critically relies on the polarity and hydrophilicity of the solvent.

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