Journal
SCIENCE CHINA-CHEMISTRY
Volume 54, Issue 11, Pages 1745-1749Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-011-4386-8
Keywords
polymer light-emitting diode; cross-linkable; electron-transporting material; water/alcohol soluble conjugated polymer
Categories
Funding
- Natural Science Foundation of China [50990065, 51010003, 51073058, 20904011]
- National Basic Research Program of China (973 Program) [2009CB623601]
- South China University of Technology
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A novel crosslinkable water/alcohol soluble conjugated polymer PFN-C containing oxetane groups and aminoalkyl groups in the side chains has been developed and used as highly efficient electron injection and transporting material for polymer light-emitting diodes (PLEDs). The unique solubility in polar solvents and crosslinkable ability of PFN-C render it a good candidate for solution processed multilayer PLEDs. It was found that PFN-C can greatly enhance the electron injection from high work-function metal cathode, due to its pendant amino groups. As a result, PLEDs with PFN-C/Al cathode exhibited comparable device performance to the devices with Ba/Al cathode. The resulting green light-emitting device showed promising performance with a maximum luminance efficiency of 13.53 cd A(-1).
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