Journal
SCIENCE CHINA-CHEMISTRY
Volume 55, Issue 1, Pages 50-54Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-011-4435-3
Keywords
iron; cross dehydrogenative coupling; terminal alkynes; benzylic ethers
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Funding
- Peking University
- National Natural Science Foundation of China [20872003]
- National Basic Research Program of China (973 program) [2009CB825300]
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Iron-mediated sp-sp(3) C-C bond formation through the cross dehydrogenative coupling (CDC) of terminal alkynes with benzylic ethers or alkanes has been developed. The inexpensive iron salt is used as the catalyst to make this transformation environmentally benign.
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