Journal
SCIENCE
Volume 341, Issue 6142, Pages 157-160Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1236259
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Funding
- Center for Re-Defining Photovoltaic Efficiency Through Molecular-Scale Control, an Energy Frontier Research Center (EFRC)
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001085]
- Natural Sciences and Engineering Research Council of Canada
- National Research Foundation of Korea [357-2011-1-C00035]
- National Science Foundation [DGE-1144155, DMR-1157490]
- State of Florida
- U.S. Department of Energy
- Florida State University
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- U.S. Department of Energy, Office of Basic Sciences [DE-SC0008832]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0961709] Funding Source: National Science Foundation
- National Research Foundation of Korea [357-2011-1-C00035] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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We describe a solid-state material formed from binary assembly of atomically precise molecular clusters. [Co6Se8(PEt3)(6)][C-60](2) and [Cr6Te8(PEt3)(6)][C-60](2) assembled into a superatomic relative of the cadmium iodide (CdI2) structure type. These solid-state materials showed activated electronic transport with activation energies of 100 to 150 millielectron volts. The more reducing cluster Ni9Te6(PEt3)(8) transferred more charge to the fullerene and formed a rock-salt-related structure. In this material, the constituent clusters are able to interact electronically to produce a magnetically ordered phase at low temperature, akin to atoms in a solid-state compound.
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