Journal
RSC ADVANCES
Volume 5, Issue 94, Pages 77417-77422Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra12700a
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Funding
- National Natural Science Foundation of China [51272231, 51229201]
- Program for Innovative Research Team in University of Ministry of Education of China [IRT13R54]
- Natural Science Foundation of Zhejiang province, China [LZ15E020001]
- Welch Foundation [AX-1730]
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A novel amino-decorated NbO-type metal-organic framework [Cu-2(C22H11NO8)(H2O)(2)]center dot(DMF)(6)center dot(H2O), (ZJU-8, ZJU = Zhejiang University; DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The activated ZJU-8a exhibits both a high C2H2 uptake capacity (195 cm(3) g(-1) at 1 bar) and a moderately high adsorption selectivity for CO2 over N-2 (12.27) and CH4 (7.38) at room temperature.
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