Journal
SCIENCE
Volume 327, Issue 5962, Pages 193-195Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1181443
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- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [20001005] Funding Source: KAKEN
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Phase transitions and the chemical composition of minerals in Earth's interior influence geophysical interpretations of its deep structure and dynamics. A pressure-induced spin transition in olivine has been suggested to influence iron partitioning and depletion, resulting in a distinct layered structure in Earth's lower mantle. For a more realistic mantle composition (pyrolite), we observed a considerable change in the iron-magnesium partition coefficient at about 40 gigapascals that is explained by a spin transition at much lower pressures. However, only a small depletion of iron is observed in the major high-pressure phase (magnesium silicate perovskite), which may be explained by preferential retention of the iron ion Fe3+. Changes in mineral proportions or density are not associated with the change in partition coefficient. The observed density profile agrees well with seismological models, which suggests that pyrolite is a good model composition for the upper to middle parts of the lower mantle.
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