4.6 Article

Dissolution and oriented aggregation: transformation from lepidorocite to goethite by the catalysis of aqueous Fe(II)

Journal

RSC ADVANCES
Volume 5, Issue 129, Pages 106396-106399

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra19787b

Keywords

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Funding

  1. National Natural Science Foundation of China [21403052, 21477032, 21277040, 21206026, 11179029]
  2. Hebei Natural Science Foundation [B2015205227, B2012205041]
  3. Hebei Province Science and Technology Support Program [15211109D]
  4. Hebei Education Department [Y2012028]

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At a low temperature, lepidocrocite-to-goethite transformation occurred in the presence of Fe(II) ions, whereas lepidocrocite was stable in the absence of Fe(II) ions. The results reveal that Fe(II) accelerates the dissolution of the lepidocrocite. The dissolved Fe(III) ions hydrolysed to form goethite. The mechanism of transformation included dissolution-reprecipitation and oriented aggregation.

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