Journal
RSC ADVANCES
Volume 5, Issue 117, Pages 96653-96659Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra20459c
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Funding
- Shorai Foundation For Science and Technology
- the Adaptable and Seamless Technology Transfer Program through target-driven R&D, Japan Science and Technology Agency (JST)
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [2401, 24102013]
- Grants-in-Aid for Scientific Research [25288053, 24102013, 26249147, 14J03877] Funding Source: KAKEN
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We report film-type scintillators based on conjugated polymers with aggregation-induced emission (AIE) properties and the modulation of their scintillation abilities by chemical modification. Alternating copolymers containing a series of boron diiminates with various substituents and comonomers were synthesized via the palladium-catalyzed cross-coupling reaction. The synthesized polymers showed AIE properties. In addition, the corresponding emission colors to photoluminescence were also obtained with X-ray excitation. These data suggest that the AIE-active polymers should be a promising platform for developing a function-tunable plastic scintillator.
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