Journal
RSC ADVANCES
Volume 5, Issue 118, Pages 97831-97835Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra20142j
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Funding
- National Basic Research Program of China (973 Program) [2012CB821702]
- National Natural Science Foundation of China [21233009, 21173221, 21571175]
- State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
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A new heterometallic MOF, namely [Cd2K4(2,3-PDC)(4)] (1) (2,3-H2PDC - 2,3-pyridine dicarboxylic acid), has been successfully synthesized from Cd2+ and K+ salts with 2,3-H2PDC under the solvothermal conditions. Single crystal X-ray diffraction studies reveal that 1 is a three-dimensional, highly connected trinodal (5,5,18)-c net. Compound 1 features a rare 3D diamondoid Cd(II)-K(I) inorganic connectivity constructed by a {Cd2K4} cluster. The K+ ion in the structure functions not only as a charge balancer but also as a connector in the construction of MOF. Tunable blue-green to white luminescence of 1 was achieved by variation of the excitation wavelength and the inclusion amount of Eu3+ ions in the host framework of 1.
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