Journal
RSC ADVANCES
Volume 5, Issue 70, Pages 56460-56469Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra09656a
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Funding
- Ministry of Education and Science of the Russian Federation [RFMEFI57414X0020]
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For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified (T = 450 degrees C, CoCl2 2 wt%). The presence of aprotic acidic centers of the iron-subgroup metal chlorides on the polymer cord was confirmed by FTIR. The catalytic effect of iron-subgroup metal chlorides is predominantly attributed to the acidic properties of the catalysts used.
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