4.6 Article

Unsymmetrically functionalized benzoporphyrins

Journal

RSC ADVANCES
Volume 5, Issue 64, Pages 51489-51492

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra09179a

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Funding

  1. U.S. Department of Energy, Office of Science, Basic Energy Sciences [DE-FG02-13ER46976]
  2. Robert A. Welch Foundation [E-680]

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The synthesis of unsymmetrical push-pull benzoporphyrins has been realized. UV-Vis and fluorescence spectroscopy, cyclic voltammetry and DFT calculations reveal subtle substituent effects on the electronic and optical properties of these porphyrins.

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