4.6 Article

High performance N-doped porous activated carbon based on chicken feather for supercapacitors and CO2 capture

Journal

RSC ADVANCES
Volume 5, Issue 44, Pages 34803-34811

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra01569c

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Funding

  1. National Natural Science Foundation of China [51372012]

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A low cost carbon precursor to produce carbon with large specific surface area and abundant heteroatoms is essential for CO2 uptake and supercapacitors to realize economic viability. We report a facile synthesis method and superior performance of a kind of porous activated carbon based on chicken feather. Herein, different activated temperatures and alkali/carbon ratios (KOH vs. carbon in g/g) are used to tailor the pore structure and the surface chemistry, so the samples show a wide range of specific surface area and nitrogen content. The sample activated at 600 degrees C with the alkali/carbon ratio of 4 is rich in nitrogen and micropores (<1 nm), exhibiting the highest CO2 uptake of 6.5 mmol g(-1) and the largest specific capacitance of 351 F g(-1) at 0.1 A g(-1). Moreover, the sample activated at 800 degrees C with the alkali/carbon ratio of 5.5 retained 260 F g(-1) at 30 A g(-1) with a retention rate of 98% after 10 000 cycles (1 A g(-1)), indicating the excellent retention capability under high current densities and long cycle life.

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