4.6 Article

Fabrication of MIL-120 membranes supported by a-Al2O3 hollow ceramic fibers for H2 separation

Journal

RSC ADVANCES
Volume 5, Issue 67, Pages 54757-54761

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra09792d

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Funding

  1. Youth Science Fund Program of Qiqihar Medical University [QY2015Q-02]
  2. Natural Science Foundation of Heilongjiang Province, China [B201110]

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The synthesis conditions of MIL-120 membranes supported by a-Al2O3 hollow ceramic fibers (HCFs) were studied systemically. The continuous and compact MIL-120 membranes were successfully synthesised by secondary growth with in situ seeding step. The MIL-120 membrane shows the separation factors of H-2-CO2, H-2-CH4 and H-2-N-2 are 9.4, 7.9, and 7.3 respectively at 293 K and 1 bar with H-2 permeance of 3.5 x 10(-7) mol m(-2) s(-1) Pa-1 as well as high thermal stability.

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