4.0 Article

Thermooxidative degradation of blends based on poly(3-Hydroxybutyrate). Specifics of the process

Journal

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
Volume 6, Issue 1, Pages 38-41

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1990793112010149

Keywords

thermal destruction; kinetics of oxygen uptake; poly(3-hydroxybutyrate); DSC; reactivity

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The relationship between the structure and the kinetics of the thermal oxidation of the poly(3-hydroxybutyrate) - ethylene propylene rubber and polyethylene - poly(3-hydroxybutyrate) systems is studied. For the first system containing 30-50 wt % poly(3-hydroxybutyrate), phase inversion is observed, which affects its reactivity. For the compositions with polyethylene, two stages of oxidation manifest themselves: before and after poly(3-hydroxybutyrate) degradation.

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