Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 88, Issue 12, Pages 2023-2028Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024414120255
Keywords
hydrogen bonds; solvation; nitrogen-containing compounds; chloroform; dichloromethane; reorganization; enthalpy of dissolution
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Enthalpies of dissolution are measured at infinite dilution of nitrogen-containing cyclic (pyrrolidine, piperidine) and aromatic compounds (aniline, N-methylaniline, N,N-dimethylaniline, N-methylimi-dazole, pyridine, 2-, 3-, 4-methylpyridine, pyrrole, N-methylpyrrole) in chloroform and dichloromethane, and vice versa (T = 298.15 K). The enthalpies of hydrogen bonds in the above systems are calculated. Relationships between resulting thermochemical data and the structure of nitrogen-containing cyclic and aromatic compounds are explored.
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