Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 86, Issue 13, Pages 2014-2017Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S003602441213002X
Keywords
Hamaker constant; nanoparticle; nanocomposite; reverse micelle; microemulsion
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In this research a new idea for prediction of ultimate sizes of bimetallic nanocomposites synthesized in water-in-oil microemulsion system is proposed. In this method, by modifying Tabor Winterton approximation equation, an effective Hamaker constant was introduced. This effective Hamaker constant was applied in the van der Waals attractive interaction energy. The obtained effective van der Waals interaction energy was used as attractive contribution in the total interaction energy. The modified interaction energy was applied successfully to predict some bimetallic nanoparticles, at different mass fraction, synthesized in microemulsion system of dioctyl sodium sulfosuccinate (AOT)/isooctane.
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