4.2 Article

A method for calculating the self-diffusion coefficients of molecules in multicomponent mixtures of liquids

Journal

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 85, Issue 3, Pages 423-426

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S003602441102004X

Keywords

self-diffusion coefficients; multicomponent liquid mixtures; Stokes Einstein equation; dynamic viscosity

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A method for calculating the self-diffusion coefficients of molecules in multicomponent liquid mixtures with arbitrary compositions was suggested. The method was based on the Stokes-Einstein equation and the assumption of the volume-additive character of the numerical multiplier in this equation. The self-diffusion coefficients of molecules of separate components in the individual state at infinite dilution in each of mixture components and dynamic viscosities of separate individual components and a mixture of a given composition are necessary and were used for calculations.

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