Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 82, Issue 12, Pages 2039-2044Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024408120121
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- Russian Foundation for Basic Research [06-03-32373]
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The problem of the diffusion of a particle in a porous medium with dead ends entering which is related to overcoming high entropy barriers is considered. Dead ends effectively decelerate migration, because, while residing in them, a particle does not participate in diffusion transfer. A new approach to the problem was suggested. The approach was based on the possibility of splitting the diffusion process into separate well-defined stages thanks to the presence of high entropy barriers. An analysis of these stages was performed using methods developed in the theory of diffusion-controlled reactions. The new approach was used to calculate the effective diffusion coefficient (characterizing the limiting particle migration deceleration caused by the presence of dead ends in a porous medium) and estimate the time of its establishment.
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