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Synthesis of new chiral schiff bases from (+)-3-carene and their use in asymmetric oxidation of sulfides catalyzed by metal complexes

Journal

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 45, Issue 6, Pages 815-824

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428009060037

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Funding

  1. Russian Foundation for Basic Research [06-03-32 052]

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A number of new chiral Schiff bases were synthesized starting from accessible monoterpene (+)-3-carene, and the products were used as ligands in metal complex-catalyzed oxidation of sulfides to chiral sulfoxides. The optical purity and the sign of optical rotation of chiral sulfoxides were found to strongly depend on the oxidation temperature.

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