Journal
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 45, Issue 7, Pages 1061-1069Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428009070136
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Supernucleophilicity of pyridine N-oxides in acyl transfer reactions was rationalized for the first time on a theoretical level. Unlike pyridines, transition state derived from pyridine N-oxides is stabilized by direct conjugation between the nucleophilic and electrophilic components.
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