Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 59, Issue 10, Pages 1109-1114Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023614100143
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Funding
- Russian Government [14.V37.21.1184]
- Siberian Branch of the Russian Academy of Sciences [38]
- [3.3763. 2011 (7-12)]
- [2014/228]
- [996]
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The X-ray diffraction structure of the high-temperature polymorph of complex sulfide EuNdCuS3 is determined. The phase we prepared has an orthorhombic structure with the unit cell parameters a = 8.0648(3) , b = 4.0207(1) , c = 15.7924(3) , space group Pnma, Z = 4, Ba2MnS3 type structure. The sample is IR transparent in the range 1800-2800 cm(-1). Thermal expansion coefficient is found to experience jumps, which are characteristic of phase transitions.
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