4.1 Article

Crystal Structures of EuLnCuS3 (Ln = Nd and Sm)

Journal

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 57, Issue 1, Pages 79-83

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023612010172

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Funding

  1. Federal Target Program Scientific and Pedagogical Personnel of Innovative Russia [6K/143-09 (P 646), NK-409/5 (P2263)]
  2. Russian Federation (Support Program for Leading Scientific Schools of the Russian Federation) [NSh-4645.2010.2]

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The compound sulfides EuLnCuS(3) (Ln = Nd and Sm) were obtained for the first time. Their crystal structures were determined from X-ray powder diffraction data. The crystals of both compounds are orthorhombic (space group Pnma). The compound EuNdCuS3 is isostructural with BaLaCuS3; the unit cell parameters are a = 11.0438(2) angstrom, b = 4.0660(1) angstrom, c = 11.4149(4) angstrom. The compound EuSmCuS3 is isostructural with Eu2CuS3; the unit cell parameters are a = 10.4202(2) angstrom, b = 3.9701(1) angstrom, c = 12.8022(2) angstrom.

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