Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 55, Issue 3, Pages 413-420Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023610030198
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Funding
- Division of Chemistry and Materials Science of the RAS
- German Academic Exchange Service (DAAD) [325-2008]
- International Science and Technology Center [3736]
- Russian Foundation for Basic Research [08-07-00318ba, 08-08-12076 ofi]
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Matrix isolation Fourier transform IR spectroscopy has been used for studying the products and mechanism of the silicon tetrafluoride reaction with water at various component ratios and reaction durations. Assignment of new bands in the spectrum confirms the earlier assumptions of first the formation of a molecular complex with water and later of trifluorosilanol, which finally condenses to give hexafluorodisiloxane.
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