Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 54, Issue 12, Pages 1947-1951Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023609120171
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Funding
- Russian Foundation for Basic Research [07-03-00637]
- Russian Federation for Support of Leading Scientific Schools [NSh-1518.2008.3]
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A new type of inner-sphere isomerism in coordination chemistry observed in metal complexes with boron cluster anions B (n) H (n) (2-) (n = 10, 12) is discussed. Specific structure of the closo-borohydride anions gives rise to edge and facial isomers, among which mirror isomers have been found. Examples of edge and facial isomers of metal complexes with the B10H (10) (2-) and B12H (12) (2-) , anions obtained experimentally and studied by X-ray diffraction are considered. Analysis of their structure revealed a new type of isomerism, which was called positional..
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