Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 84, Issue 6, Pages 1095-1100Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363214060073
Keywords
oxidative polymerization; p-phenylenediamine; polyquinoxaline; polyaniline; pernigraniline; 1,4-benzquinonediimine
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Oxidative polymerization of p-phenylenediamine in a hydrochloric acid solution yields not a polyquinoxaline polymer as described in the literature but a modified poly(1,4-benzoquinonediimine-N,N'-diyl-1,4-phenylene) analogous to polyaniline known as pernigraniline. A new scheme of oxidative polymerization of p-phenylenediamine was suggested.
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