Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 82, Issue 7, Pages 1191-1196Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363212070018
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Funding
- Russian Foundation of Basic Research [09-03-00853]
- Federal Target Program Scientific and educational-scientific staff of innovation Russia [P 58]
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Layered perovskite-type oxides A(2)Ln(2)Ti(3)O(10) (A = Li, Na, K; Ln = La, Nd) prepared by solid-phase synthesis and their hydrated forms were characterized by the methods of TGA, XRD, and by UV-Vis spectroscopy. Photocatalytic activity of A(2)Ln(2)Ti(3)O(10) oxides in reaction of hydrogen evolution from aqueous alcoholic suspensions irradiated by UV-light was studied. It was shown that the ability to intercalation of water into interlayer space essentially affects the rate of photoinduced hydrogen evolution and is a determining factor leading to a high photocatalytic activity.
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