Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 79, Issue 5, Pages 1001-1003Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363209050235
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In contrast to 2,2,6,6-tetramethylpiperidine and other aliphatic amines, at the electrochemical oxidation of 1-chloro-2,2,6,6-tetramethylpiperidine a sufficiently stable cation-radical is formed. Its formation is confirmed by the data of cyclic voltammetry and electron paramagnetic resonance. Further transformation of the cation-radical leads to the formation of 2,2,6,6-tetramethylpiperidin-1-oxyl.
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