Journal
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
Volume 48, Issue 9, Pages 905-910Publisher
PLEIADES PUBLISHING INC
DOI: 10.1134/S1023193512040039
Keywords
corrole; voltammetry; electroreduction; molecular oxygen
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Funding
- Federal Target Project Scientific and Scientific-Pedagogical Human Resources of Innovative Russia
- Russian Foundation for Basic Research [12-03-97542-r_center_]
- [02.740.11.0253]
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The method of cyclic voltammetry (CV) was used to compare electrochemical and electrocatalytic properties of meso-triphenylcorrole [H-3(ms-Ph)(3)Cor] and also its complexes with Mn(III), Co(III), Cu(III), and Zn(II) in 0.1M KOH. Metal-localized redox transitions are detected in the complexes of Mn (III -> IV) and (III -> II), Co (III -> II), Cu (III -> II). It is shown that the manganese complex features most effective catalytic properties in the reaction of molecular oxygen electroreduction.
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