Journal
RSC ADVANCES
Volume 5, Issue 60, Pages 48558-48562Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra06337j
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Funding
- National Natural Science Foundation of China [NSFC 21272009]
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A Pd-catalyzed Cu-mediated desulfurative Sonogashira cross-coupling reaction of thioamide-type quinolone derivatives was proposed for the construction of C-sp(2)-C-sp bonds. Alkynylated quinoline derivatives can be easily synthesized in moderate to excellent yields. The mechanism and effect of the 3-cyano on the reaction were also discussed.
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