Journal
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
Volume 44, Issue 8, Pages 967-971Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1023193508080144
Keywords
oxygen; superoxide ion; electroreduction; powder microelectrode
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Funding
- Natural Science Foundation of Henanu Province of China [072300420010]
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In this paper, the powder microelectrode technique was employed in studying the voltametric response of the O-2/O-2(-) couple, which demonstrated a nearly reversible redox process at an acetylene black powder microelectrode in N,N-dimethylformamide (DMF). A well-developed steady state current plateau for the electrochemical reduction of oxygen was obtained in this system. The electron transfer number (n) and heterogeneous electron transfer rate constant k(s) were measured by steady-state voltametric response, and the results were 1.08, 3.4 x 10(-3) cm s(-1), respectively. Additionally, the scavenging activity of O-2(-) with biological antioxidant (ascorbic acid) was evaluated by cyclic voltammetry; IC50 came to 5 x 10(-4) mol/l.
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