Journal
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
Volume 38, Issue 9, Pages 589-595Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070328412080015
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Funding
- Council on Grants at the President of the Russian Federation [MK-977.2012.3]
- Federal target program Research and Developments on Priority Directions of the Scientific Technological Complex of Russia [16.552.11.7010, 2011-5.2-552-001]
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Cationic-anionic chloride complexes of gold(III), [(L)AuCl2]BF4 (L = 2,2'-bipyridine and 1,10-phenanthroline (Phen)), are synthesized. Their reactions and the reactions of complex [(Phen)AuCl2]Cl with silver(I) and sodium acetates are studied. The chloride ligands in complexes [(L)AuCl2]BF4 are easily substituted by the acetate ligands in the reaction with silver(I) acetate to form new carboxylate complexes [(L)Au(OAc)(2)]BF4. The reaction of complex [(Phen)AuCl2]Cl with sodium acetate in glacial acetic acid affords binary complex salt [(Phen)AuCl2][AuCl4], which is characterized by single-crystal X-ray diffraction analysis.
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