4.1 Article

Stabilization of silicon nanoparticles by carbenes

Journal

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
Volume 36, Issue 5, Pages 330-332

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070328410050027

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Funding

  1. Russian Foundation for Basic Research-Israel Ministry of Science and Technology [06-03-72009]

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Sodium reduction of a mixture of tetrabromosilane with imidazole ionic liquids in organic solvents gives dispersions of silicon nanoparticles stabilized by carbene ligands. It was shown that the size of silicon nanoclusters depends on the size of substituents at nitrogen atoms of 1,3-dialkylimidazol-2-ylidenes.

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