4.6 Article

A practical anodic oxidation of aminofurazans to azofurazans: an environmentally friendly route

Journal

RSC ADVANCES
Volume 5, Issue 47, Pages 37617-37625

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra05726d

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Funding

  1. Russian Science Foundation [14-13-01153, 14-13-00884]
  2. Russian Foundation for Basic Research [12-03-00517a]
  3. Russian Science Foundation [14-13-01153] Funding Source: Russian Science Foundation

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Nickel oxyhydroxide, NiOOH, anode has been shown to be an effective tool for the oxidation of aminofurazans to azofurazans in ca. 1% aqueous alkali at room temperature. The electrochemical reaction is simple and convenient, eliminating the use of expensive and toxic organic or inorganic oxidants. The green economic preparation of desired azo compounds is very clean, producing only H-2 as a result of cathodic reduction.

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