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Chemosensors for detection of nitroaromatic compounds (explosives)

Journal

RUSSIAN CHEMICAL REVIEWS
Volume 83, Issue 9, Pages 783-819

Publisher

ND Zelinsky Inst Organic Chemistry, RAS - ZIOC RAS
DOI: 10.1070/RC2014v083n09ABEH004467

Keywords

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Funding

  1. Ministry of Education and Science of the Russian Federation [GK 14.A18.21.0817]
  2. Council for Grants at Russian Federation President [MK-1511.2013.3]
  3. Russian Federation Government [02.A03.21.0006, 211]

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The key types of low-molecular-mass chemosensors for the detection of nitroaromatic compounds representing energetic substances (explosives) are analyzed. The coordination and chemical properties of these chemosensors and structural features of their complexes with nitroaromatic compounds are considered. The causes and methods for attaining high selectivity of recognition are demonstrated. The primary attention is paid to the use of low-molecular-mass chemosensors for visual detection of explosives of this class by colorimetric and photometric methods. Examples of using photo- and chemiluminescence for this purpose are described. A separate section is devoted to electrochemical methods of detection of nitroaromatic compounds. Data published from 2000 to 2014 are mainly covered. The bibliography includes 245 references.

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