Journal
RUSSIAN CHEMICAL REVIEWS
Volume 82, Issue 9, Pages 835-864Publisher
TURPION LTD
DOI: 10.1070/RC2013v082n09ABEH004342
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Data on fluoroalkylation and perfluoroalkylation methods in organic synthesis are analyzed, summarized and described systematically. The most practically important properties of compounds with fluoroalkyl substituents are illustrated. The key trends and the potential of this field of organic chemistry are considered. Electrochemical syntheses of perfluoroalkyl derivatives that are inaccessible or experimentally difficult to prepare by regular chemical techniques are presented. Particular attention is paid to processes involving organometallic compounds as well as to prospects for the development of this field of research. The bibliography includes 226 references.
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