Journal
RUSSIAN CHEMICAL REVIEWS
Volume 79, Issue 12, Pages 1123-1143Publisher
TURPION LTD
DOI: 10.1070/RC2010v079n12ABEH004140
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Funding
- Presidium of the Russian Academy of Sciences [P21]
- Ministry of Education and Science of the Russian Federation [16.740.11.0211]
- Ministry of Education, Youth and Sports of the Czech Republic (Czech-Russian) [ME 847]
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The synthesis and properties of the most popular and widely used electrically conducting polymer, polyaniline, are considered. The proposed mechanisms of the molecular synthesis and self-assembly of macromolecules occurring during the polymerization agree with the large body of experimental data. The reaction medium acidity is demonstrated to affect the mechanism of aniline oxidative polymerization and the formation of different types of supramolecular structures, namely, nanoglobules, nanofibres, nanotubes and microspheres. The bibliography includes 250 references.
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