Journal
RUSSIAN CHEMICAL REVIEWS
Volume 78, Issue 4, Pages 319-328Publisher
TURPION LTD
DOI: 10.1070/RC2009v078n04ABEH003904
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Funding
- Division of Chemistry and Materials Science of the RAS
- RF Ministry of Education and Science [NSh-5236-2006.3]
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Mercury isotope effects in environmentally significant chemical and biochemical reactions are considered. The recently discovered anomaly for the Hg-199 and Hg-201 magnetic nuclei proves that both chemical and biochemical transformations of mercury compounds (outside and inside living organisms) follow radical spin-selective mechanisms. The regularities of isotope fractionation in natural photochemical processes and in living tissues are discussed. The bibliography includes 22 references
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