Journal
RUSSIAN CHEMICAL BULLETIN
Volume 63, Issue 8, Pages 1837-1842Publisher
SPRINGER
DOI: 10.1007/s11172-014-0673-9
Keywords
acetylcholine; hydroperoxides; free radicals; lipid oxidation; method of inhibitors
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Funding
- Russian Foundation for Basic Research [14-03-00757]
- Council on Grants at the President of the Russian Federation (Program for State Support of Leading Scientific Schools of the Russian Federation) [NSh 5226-2014-03]
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In organic solvents, acetylcholine chloride accelerates lipid oxidation and hydroperoxide decomposition to free radicals similarly to cationic surfactants. The rates of radical formation in the reaction of acetylcholine with cumyl, tert-butyl, and limonene hydroperoxides and hydrogen peroxide at 37 A degrees C were estimated by the inhibitor method using different radical acceptors. In an aqueous medium, hygroscopic acetylcholine does not react with hydroperoxides.
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