Journal
RUSSIAN CHEMICAL BULLETIN
Volume 62, Issue 9, Pages 1991-1998Publisher
SPRINGER
DOI: 10.1007/s11172-013-0289-5
Keywords
boron difluoride beta-diketonates; crystal structure; stacking factor; excimer
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The crystal structure of 4-(4-benzoyloxy-2-hydroxyphenyl)-2,2-difluoro-6-phenyl-1,3,2-dioxaborine (1) was determined by X-ray diffraction analysis. pi-pi-Stacking interaction between the molecules results in joining the molecules into a three-dimensional layered framework. Luminescence of the aggregates is observed in concentrated solutions of compound 1. Two routes of excimer formation in crystal were revealed by steady-state and time-resolved luminescence spectroscopy: via excitation of single molecules and via excitation of aggregates.
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