4.1 Article

CuCl-Catalyzed ring-opening isomerization of gem-chlorofluorocyclopropanes with the formation of chlorofluoroalkenes and chlorofluoroalkadienes

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 62, Issue 1, Pages 71-82

Publisher

SPRINGER
DOI: 10.1007/s11172-013-0009-1

Keywords

gem-chlorofluorocyclopropanes; catalytic isomerization; copper(I) chloride; three-membered ring opening; chlorofluoroalkenes; chlorofluoroalkadienes

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The ability of copper(I) chloride to catalyze the ring-opening isomerization of alkyl-, phenyl-, vinyl-, and cyclopropyl-substituted gem-chlorofluorocyclopropanes to chlorofluoroalkenes or chlorofluoroalkadienes was found.

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