4.1 Article

Highly efficient atom economical green chemistry synthesis of vinyl sulfides from thiols and acetylene in water

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 62, Issue 2, Pages 438-440

Publisher

SPRINGER
DOI: 10.1007/s11172-013-0059-4

Keywords

acetylene; thiols; vinyl sulfides; vinylation; water; green chemistry

Funding

  1. Russian Foundation for Basic Research [11-03-00334]
  2. Council on Grants of the Russian Federation [NSh-1550-2012.3]

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Potassium thiolates generated by treatment of thiols with aqueous KOH react with acetylene to give the corresponding vinyl sulfides in 90-95% yields.

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