Journal
RUSSIAN CHEMICAL BULLETIN
Volume 62, Issue 11, Pages 2487-2494Publisher
SPRINGER
DOI: 10.1007/s11172-013-0360-2
Keywords
aminomethylphosphines; benzonitriles; 1,5-diaza-3,7-diphosphacyclooctanes; aminals
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Funding
- Russian Foundation for Basic Research [12-03-97083-r_povolzh'e_a]
- Council on Grants at the President of the Russian Federation (Program of State Support for Leading Scientific Schools of the Russian Federation) [NSh-6667.2012.3]
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A condensation of bis(hydroxymethyl)arylphosphines with 3- and 4-aminobenzonitriles leads to the corresponding 3,7-diaryl-1,5-bis(cyanophenyl)-1,5-diaza-3,7-diphosphacyclo-octanes. Acyclic (aryl) bis[N-(2-cyanophenyl)aminomethyl]phosphines are formed in the case of 2-aminobenzonitrile. Molecular and crystalline structure of the compounds obtained was studied by X-ray diffraction analysis.
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